This is Aleck Wang. I’m leading the chemistry group (Photo
1) during the cruise. We are in charge of measurements of seawater carbonate chemistry
during this cruise. The seawater carbonate system can be characterized by four
primary parameters: pH, partial pressure of carbon dioxide (pCO2), total carbon dioxide
(TCO2), and total alkalinity (TA). We measured all of them. As a
comparison, we also made similar measurements during a sister cruise last year
in the North Atlantic Ocean at similar latitudes.
Photo 1 (by Taylor Crockford): The chemistry group: (from left) Kelly Knorr, Elliott Roberts, Aleck Wang, Nick Tuttle, Katherine Hoering, and Sophie Chu. |
Let’s talk about the difference in seawater chemistry
between the two ocean basins: North Atlantic vs. North Pacific. This is
important because it sets the background and logic for this ocean acidification
– pteropods project.
Naturally, seawater in the North Pacific Ocean is more
acidic (lower in pH) than in the North Atlantic Ocean. This is related to the
circulation, biology and chemistry in the ocean, which involve complicated
processes that oceanographers have been studying for decades. The results of
these processes are that seawater in the North Pacific in general has lower pH,
but higher TCO2 concentrations than that of the North Atlantic at
similar latitude (Figure 1; data collected in August 2011 and August 2012 by
Wang’s group through this project).
Figure 1. pH and TCO2 profiles at two stations in the
North Pacific vs. North Atlantic. Data were collected by Wang’s group through
this project.
Such a difference causes profound differences in seawater
chemistry between the two ocean basins. For example, aragonite compensation
depth in the North Pacific is dramatically shallower than the North Atlantic.
Aragonite, one type of calcium carbonate minerals, is required by many marine
animals (e.g. pteropods, shrimps, and many species of bi-valves) to form their
shells. Aragonite can dissolve or precipitate in seawater, depending on its
solubility measured by saturation state: if aragonite saturation state is
greater than 1, the condition favors aragonite precipitation and growth of
shell-building animals; otherwise, aragonite would dissolve, which can have
detrimental effects on shell building animals. The water depth where aragonite
saturation state equals 1 is called aragonite compensation depth. Above this
depth, aragonite saturation is greater than 1 and less than 1 otherwise.
Figure 2. Profiles of aragonite saturation state in the North
Pacific vs. North Atlantic
Lower aragonite saturation state in the North Pacific is primarily
due to lower pH condition as compared to the North Atlantic (Figure 2; data
collected by Wang’s group through this project). As a result, the aragonite
compensation depth is ~135 m at a North Pacific station (blue line in Figure 2)
as compared to 2500 m at a North Atlantic station (green line in Figure 2). As
the ocean continues acidifying as more CO2 dissolves into the ocean
due to the rise of atmospheric CO2 concentration, seawater pH will
continue dropping and aragonite compensation depth will become shallower in all
ocean basins in the coming decades. In the North Pacific, this becomes an imminent
problem for many shell-building animals, as the aragonite compensation depth
inches up to the surface each year and the water layer supports their shell
formation become narrower.
This ocean acidification project takes advantage of the very
difference in carbonate chemistry between the North Atlantic and North Pacific
to examine how such a difference affects pteropod’s life style and
distribution. More about pteropod biology will follow. The results from this
project will inform us what would happen to pteropods as ocean acidification
continues. Essentially, the North Atlantic servers as a control case in this
study to compared with, and the North Pacific is the acidified case.
The other goal of this project is to evaluate and
compare the ocean acidification rates in the two ocean basins by comparing our
measurements of carbonate parameters with historical data. Because of the
difference in seawater chemistry between the two ocean basins, their
acidification rates likely differ. This will help us to predict future changes
in seawater chemistry.
The chemistry group (Photo 2) has done a marvelous job on
making high quality measurements of carbonate chemistry during both North
Atlantic and North Pacific cruises, as shown in Figures 1 and 2. Special thanks
go to each group member.
Photo 2 (by Taylor Crockford): The chemistry group around the CTD-Rosette package. |
Curious to know if one of the two oceans, either, were more subject to historical ships sunk because of water warfare - during Revolution, or WWI or II, so that sunken ship rusting, etc, has caused the chemical differences, a.k.a., the acidification of one ocean more than the other.
ReplyDeleteRead once that many, many ships remain in the ocean, deteriorating slowly, from all of the last 300 years of activity between America and Europe. Perhaps those ships need lifting to clean the ocean and restore its integrity?
It is and interesting hypothesis but I doubt there is enough ships to have an important weight in the acidification of the oceans, especially considering the fact that they sunk all the way to the bottom of the oceans and down there the pH is already way lower than say the cap of 1000m in the pacific. Most of the ''acidification'' comes from the atmospherical CO2 being precipitated in the ocean waters.
DeletePS: This is my personnal interpretation of the matter, therefore I might as well be wrong!
How can you write a post comparing the chemistry of two oceans without using the words "salinity" or "salt"!
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